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Isotope selective ir-laser multffhoton dissociation of CF3Cl and selectivity enhancement with substrate pressure

✍ Scribed by S.K. Sarkar; V. Parthasarathy; A. Pandey; K.V.S. Rama Rao; Jai P. Mittal

Publisher: Elsevier Science
Year: 1981
Tongue: English
Weight: 375 KB
Volume: 78
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(81)85241-4

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✦ Synopsis

Photolysis of CF3CI with a 9.6 pm CO2 laser has indicated that carbon-13 selectsvrty increases when the excitation frequency is sliihtly red-shifted from the ~1 band centreat R(18). A selectmrty enhancement with substrate pressure was aiso observed if the P(l8) line, which is far red-shifted, is used at low fluence.

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