Isotope effects on kinetic energy release. Elimination of CH4 from [CH3CHOH]+ and [CH2OCH3]+
β Scribed by Kevin F. Donchi; Einar Uggerud; Georg Hvistendahl; Peter J. Derrick
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 488 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0168-1176
No coin nor oath required. For personal study only.
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The kinetic isotope effect for the abstraction of hydrogenideuterium from dimethylnitramine and dimethylnitramine-ds by chlorine atoms has been studied in the temperature range 273-353 K. The rate constant ratio k H / k D is given by the Arrhenius expression, k H / k o = (0.92 t-0.07)exp(286 ? 250/R