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Isotope effects in the oxidative functionalization of methane in the presence of rhodium-containing homogeneous catalytic systems

✍ Scribed by E. G. Chepaikin; A. P. Bezruchenko; G. N. Boiko; A. E. Gekhman; I. I. Moiseev

Book ID
110170687
Publisher
Springer
Year
2006
Tongue
English
Weight
168 KB
Volume
47
Category
Article
ISSN
0023-1584

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## Abstract The carbon kinetic isotope effect in the reaction of CH~4~ with OH has an experimentally measured value of 1.003. The measurement was performed using a static system in which the source of OH was the gas‐phase photolysis of H~2~O~2~ with ultraviolet light produced by a high‐pressure mer