✦ LIBER ✦

Isotope effects in fragmentation

✍ Scribed by Peter J. Derrick

Publisher: John Wiley and Sons
Year: 1983
Tongue: English
Weight: 884 KB
Volume: 2
Category: Article
ISSN: 0277-7037
DOI: 10.1002/mas.1280020204

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Isotope effects and H/D scrambling in th

Isotope effects and H/D scrambling in the fragmentation of labelled propenes

✍ A. Y.-K. Lau; B. H. Solka; A. G. Harrison 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 English ⚖ 214 KB

The fragmentation reaction [C,(H, D)J+. + [C,(H, D)J+ + (H, D) has been examined in the metastable decomposition region for two pairs of labelled propenes: CH,CD=CH,, CD,CH==CD, and CD,CH=CH,, CH,CD=CD,. The results indicate that complete hydrogen scrambling occurs in the propene molecular ion prior

Isotope effects upon kinetic energy rele

Isotope effects upon kinetic energy release in metastable ion fragmentations

✍ M. Bertrand; J.H. Beynon; R.G. Cooks 📂 Article 📅 1972 🏛 Elsevier Science ⚖ 420 KB

Nucleophile Isotope Effects

✍ Vernon E. Anderson; Adam G. Cassano; Michael E. Harris 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 8 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Secondary Isotope Effects

✍ Alvan C. Hengge 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 8 KB

Quantum effects and isotope effects in c

Quantum effects and isotope effects in chemical kinetics

✍ S. G. Christov; M. Parlapanski 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 English ⚖ 984 KB

## Abstract The relations of quantum and kinetic isotope effects are investigated using the exact quantum corrections to the collision and activated complex theories. The latter are computed for the collinear three‐atomic reaction H~2~ + H → H + H~2~ and the related isotopic reactions using realist

Kinetic isotope effects on metaphosphate

Kinetic isotope effects on metaphosphate generation from fragmentation of 2,3-oxaphosphabicyclo[2.2.2]octene derivatives

✍ Stefan Jankowski; Juliusz Rudziński 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 556 KB

Kinetic isotope effects of deuterium and oxygen-1 8 were measured on fragmentation of syn-3-ethoxy (la) The secondary deuterium isotope effect on hydrogen adjacent to the P-C bond was found to be 1.060 & 0.008 for la and 1.081 f 0.009 for lb. The kinetic oxygen isotope effect on the bridge P-0-C is