✦ LIBER ✦

Isotope and centrifugal coupling effects on VV and VT rate constants for energy transfer in hydrogen

✍ Scribed by Mario Cacciatore; Rosanna Caporusso; Gert D. Billing

Publisher: Elsevier Science
Year: 1992
Tongue: English
Weight: 464 KB
Volume: 197
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(92)86028-g

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✦ Synopsis

By using a semi-classical model, which explicitly includes the centrifugal stretch coupling term, for vibrational transitions in diatomic molecules we have investigated the importance of this term. Calculations of VV and VT rates for vibrational transitions in deuterium are compared with experimental data and previous calculations on hydrogen in order to explore isotopic effects.

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