𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Isothermal physical aging of a fully cured epoxy—amine thermosetting system

✍ Scribed by Shellee L. Maddox; John K. Gillham


Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
362 KB
Volume
64
Category
Article
ISSN
0021-8995

No coin nor oath required. For personal study only.

✦ Synopsis


The rate and effects of isothermal physical aging of a fully cured epoxyamine/glass fiber composite specimen were studied for a wide range of isothermal aging temperatures (0180 to 200ЊC) using a freely oscillating torsion pendulum technique: torsional braid analysis (TBA). As assigned from the maxima in the mechanical loss vs. temperature, the glass transition temperature, T g , was 182ЊC (0.9 Hz), and the principal glassy-state secondary transition temperature, T b , was É 030ЊC (1.9 Hz). Plots of the increase in the isothermal modulus and of the decrease in the isothermal mechanical loss were linear vs. log aging time; their slopes provided aging rates. It was found that the isothermal aging rate varies with isothermal aging temperature (T a ) and that there are two maxima in the aging rate vs. T a . A correlation presumably exists between the two maxima in the aging rate and the two transitions. This is not surprising since mechanical loss maxima (i.e., transitions) and aging rate maxima both correspond to specific, localized, and restricted submolecular motions. Effects after isothermal physical aging were investigated vs. temperature in terms of change of modulus of the specimen. The effect of isothermal aging existed primarily in a narrow temperature region localized about T a . The majority of the isothermal aging effect can be eliminated by heating to temperatures above T a but below T g . Theoretical and practical implications of this observation are discussed.


📜 SIMILAR VOLUMES


Evolution of properties with increasing
✍ Jong Keun Lee; John K. Gillham 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 214 KB 👁 2 views

## Abstract Isothermal physical ageing below the glass‐transition temperature (__T__~__g__~) of a high‐__T__~__g__~ thermosetting difunctional epoxy/tetrafunctional aromatic amine system was investigated at different ageing temperatures (__T__~__a__~) and chemical conversions (monitored by the __T_

Aging behavior of a hot-cured epoxy syst
✍ Davis Fata; Wulff Possart 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 146 KB 👁 1 views

## Abstract The thermal and hydro‐thermal aging of a hot‐cured epoxy system (diglycidylether of bisphenol A (DGEBA) + dicyandiamide (DDA)) in the glassy state is revisited using DSC and IR attenuated total reflection spectroscopy. Because of the diffusion of DDA from the solid particles into the li

Evolution of properties of an isocyanate
✍ M. T. DeMeuse; J. K. Gillham; F. Parodi 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 217 KB 👁 2 views

The present article describes a methodology for examining the evolution of the properties vs. cure of a complex thermosetting isocyanate/epoxy reactive mixture which reacts through two consecutive but separable reaction regimes. The methodology is based on the use of the torsional braid analysis (TB