Isotactic polycondensation of l-lactic acid with biogenic creatinine
✍ Scribed by Wei Jiang; Wei Huang; Na Cheng; Yunbiao Qi; Xupeng Zong; Hong Li; Quanxing Zhang
- Book ID
- 119351883
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 386 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0032-3861
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## Abstract **Summary:** Stereoblock poly(lactic acid) consisting of D‐ and L‐lactate stereosequences can be successfully synthesized by solid‐state polycondensation of a 1:1 mixture of poly(L‐lactic acid) and poly(D‐lactic acid). In the first step, melt‐polycondensation of L‐ and D‐lactic acids is
Poly(L-lactic acid) (PLLA) was produced by the melt polycondensation of L-lactic acid. For the optimization of the reaction conditions, various catalyst systems were examined at different temperature and reaction times. It was discovered that Sn(II) catalysts activated by various proton acids can pr