## Abstract The cyclobismuthanes R~__n__~Bi~__n__~, [R = 2‐(Me~2~NCH~2~)C~6~H~4~; __n__ = 3 (1a), 4 (1b)] have been synthesised by reduction of RBiCl~2~ with Na in liquid NH~3~ or by reaction of R~2~BiCl with LiAlH~4~ in Et~2~O. The reaction of 1a/b with W(CO)~5~·THF afforded the bismuthinidene com
Isomers of a Dibismuthane, R 2 Bi−BiR 2 [R = 2,6-(Me 2 NCH 2 ) 2 C 6 H 3 ], and Unusual Reactions with Oxygen: Formation of [R 2 Bi] 2 (O 2 ) and R‘R‘ ‘Bi [R‘ = 2-(Me 2 NCH 2 )-6-{Me 2 N(O)CH 2 }C 6 H 3 ; R‘ ‘ = 2-(Me 2 NCH 2 )-6-{O(O)C}C 6 H 3 ]
✍ Scribed by Balazs, Lucia; Breunig, Hans J.; Lork, Enno; Soran, Albert; Silvestru, Cristian
- Book ID
- 126166296
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 277 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0020-1669
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