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Isomerization of olefins catalysed by Cp2TiCl2/Mg

โœ Scribed by Yanlong Qian; Guisheng Li; Xiaofan Zheng; Yao-Zeng Huang


Publisher
Elsevier Science
Year
1993
Weight
252 KB
Volume
78
Category
Article
ISSN
0304-5102

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CP2TiCl2-catalyzed hydroalumination of i
โœ Arnaud Parenty; Jean-Marc Campagne ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 75 KB

The reduction of alkynols with LiAlH 4 in diglyme is a long known process leading to the formation of (E)-alkenols. We have, by serendipity, found that, in the presence of a catalytic amount (10%) of Cp 2 TiCl 2 , the stereoselectivity of the reaction is reversed, leading to the selective formation