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Isomerization of OH-Isoprene Adducts and Hydroxyalkoxy Isoprene Radicals

โœ Scribed by Dibble, Theodore S.


Book ID
127088045
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
160 KB
Volume
106
Category
Article
ISSN
1089-5639

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๐Ÿ“œ SIMILAR VOLUMES


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## Abstract Rate constants for several intermediate steps in the OHโ€initiated oxidation of isoprene were determined using laserโ€photolysis/laserโ€induced fluorescence of OH radicals at total pressures between 3 and 4 Torr at 295 K. The rate constant for decomposition of the hydroxyalkoxy radical was

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## Abstract Calculations are carried out on the รƒ state of HO~2~, CH~3~O~2~, and CH~3~CH~2~O~2~ and 10 isomers and conformers of the isopreneโ€OHโ€O~2~ peroxy radicals derived from OH addition to isoprene (2โ€methylโ€1,3โ€butadiene). In addition to calculating vertical and adiabatic excitation energies,