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Isomerization of cyclopropane to propylene in shock waves

✍ Scribed by Yoshiaki Hidaka; Takashi Oki

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 256 KB
Volume: 141
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(87)85011-x

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✦ Synopsis

Cyclopropane mixtures diluted with argon were heated to temperatures in the range 1 loo-1450 K behind incident and reflected shock waves. The rate of isomerization of cyclopropane to propylene was measured by tracing the time variation of absorption at 3.39 pm. The rate constant expression k=4.60~ 10 14exp( -62.5 kcal/RT) s-' was determined, in accord with extrapolation from lower-temperature experiments.

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