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Isomerization of 4-Amino-6,7-diphenylbicyclo[2.2.2]octan-2-ones.

โœ Scribed by Werner Seebacher; Robert Saf; Reto Brun; Marcel Kaiser; Robert Weis

Publisher
John Wiley and Sons
Year
2007
Weight
17 KB
Volume
38
Category
Article
ISSN
0931-7597

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Improved conversion of 6-endo-tosyloxybi
Improved conversion of 6-endo-tosyloxybicyclo[2.2.2]octan-2-ones into 6-exo-acetoxy and 6-exo-benzoyloxybicyclo[2.2.2]octan-2-ones
โœ Rinaldo Marini Bettolo; Luisa Maria Migneco; Piergiogio Moretti; Rita Scarpelli ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 37 KB ๐Ÿ‘ 1 views

The reaction conditions for the conversion of 6endo-tosyloxybicyclo[2.2.2]octan-2-one (7b) into 6-exo-acetoxy (8b) and 6-exo-benzoyloxybicyclo[2.2.2]octan-2-one (8a), respectively, were improved. Thus known 6-endo-tosyloxy-bicyclo[2.2.2]octan-2-ones (+)-(1RS,6SR,8SR,11RS)-11-[(4-toluenesulfonyl)oxy]