Isomerization of 3-vinyl- and 3-ethynyl-o-carboranes to 2- and 4-vinyl and 2- and 4-ethynyl-m-carboranes
โ Scribed by V. N. Kalinin; N. I. Kobel'kova; L. I. Zakharkin
- Book ID
- 112445255
- Publisher
- Springer
- Year
- 1982
- Tongue
- English
- Weight
- 277 KB
- Volume
- 31
- Category
- Article
- ISSN
- 1573-9171
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Current interest in biologically active B,y-unsaturated a-amino acids' prompts us to report syntheses of a-ethynyl-3,4\_dihydroxyphenylalanine 5 and a-vinyl-3,4\_dihydroxyphenylalanine g -to our knowledge the first examples of a-substituted-a-amino acids bearing unsaturation attached to the quaterna
## Abstract It is shown that 2โvinylโ1,3โdioxan can be synthesized by the methods of __Faass__ and __Hilgert__^1^ and of __Fisher__ and __Smith__^2^. From 2โvinylโ1,3โdioxan we obtained 2โethylโ1,3โdioxan and 2โ(1โฒ,2โฒโdibromoethyl)โ1,3โdioxan. 4โVinylโ1,3โdioxan and 2โvinylโ1,3โdioxan have the same