Isomerization of 1-cyclopentylmethylamine
โ Scribed by H. E. Audier; J. P. Denhez; A. Milliet; G. Sozzi
- Publisher
- John Wiley and Sons
- Year
- 1984
- Tongue
- English
- Weight
- 160 KB
- Volume
- 19
- Category
- Article
- ISSN
- 1076-5174
No coin nor oath required. For personal study only.
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## Abstract The thermal isomerization of 1,1โdivinylcyclopropane has been investigated in the gas phase in the temperature range of 238 to 288ยฐC and for pressures in the range of 4 to 12 torr. The isomerization to 1โvinylcyclopentene is homogeneous and kinetically first order and almost certainly u
## Abstract Rate constants for the unimolecular thermal isomerization of gaseous 1,1โdimethylcyclopropane to isomeric methylbutenes have been measured, and Arrhenius parameters determined, over a wide temperature range, 683โ1132 K, using a singleโpulse shock tube and a static reactor. For the overa
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