Reaction of alkylbrolnides with NaZIYe under carbon monoxide atmosphere followed by CuCl treatment gives the corresponding 1,2-diketones in 70-9056 yields. Although several methods are avatlable for tire synthesis of 1,2-diketones, efforts are continuing for the development of new, more convenient a
Isomerization of 1-alkenes using the Na2Fe(CO)4/CuCl and Na2Fe(CO)4/BrCH2CH2 Br reagent systems
β Scribed by Malladi Rama Reddy; Mariappan Periasamy
- Book ID
- 107812687
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 302 KB
- Volume
- 491
- Category
- Article
- ISSN
- 0022-328X
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Diethyl 1,1-cyclopropanedicarboxylate undergoes nucleophilic ring opening with Na2Fe(C0)4\*3/2 dioxane under CO at room temperature to produce a variety of carbonylated products. Transition metal promoted rearrangements of small ring organic compounds continue to receive intense examinati0n.l The co
## Abstract The reaction of the title cyclic complex (1) with sodium amalgam in THF resulted in the expected cleavage of the FeβFe bond to afford bisβsodium salt (Me~2~SiSiMe~2~) [Ξ·^5^βC~5~H~4~Fe (CO)~2~Na]~2~ (4). The latter was not isolated and was used directly to react with MeI, PhCH~2~Cl, CH~3