1,2-Diketones from alkylbromides using na2fe(co)4/cucl system
β Scribed by Arockiasamy Davasagayaraj; Mariappan Periasamy
- Book ID
- 104224970
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- French
- Weight
- 152 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Reaction of alkylbrolnides with NaZIYe under carbon monoxide atmosphere followed by CuCl treatment gives the corresponding 1,2-diketones in 70-9056 yields. Although several methods are avatlable for tire synthesis of 1,2-diketones, efforts are continuing for the development of new, more convenient and efficient methods for the synthesis of this important class of compounds.1-4 Recently,
π SIMILAR VOLUMES
Diethyl 1,1-cyclopropanedicarboxylate undergoes nucleophilic ring opening with Na2Fe(C0)4\*3/2 dioxane under CO at room temperature to produce a variety of carbonylated products. Transition metal promoted rearrangements of small ring organic compounds continue to receive intense examinati0n.l The co