Isomer-specific spectra and ionization p
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Thomas Troxler; Richard Knochenmuss; Samuel Leutwyler
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Article
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1989
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Elsevier Science
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English
⚖ 407 KB
van der Waals clusters exhibit spectroscopically distinct isomers for n = 2 and 4. The ionization potentials (IP)oftheseisomersdifferby33(n=2)and56cm-'(n=4),orabout25%ofthetotalIPshiffinducedbytheclu~ter.Based on this IP difference, isomer-selective ionization and electronic spectroscopy have been p