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Isomer-specific spectra and ionization potentials of van der Waals clusters

✍ Scribed by Thomas Troxler; Richard Knochenmuss; Samuel Leutwyler

Publisher: Elsevier Science
Year: 1989
Tongue: English
Weight: 407 KB
Volume: 159
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(89)87531-1

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✦ Synopsis

van der Waals clusters exhibit spectroscopically distinct isomers for n = 2 and 4. The ionization potentials (IP)oftheseisomersdifferby33(n=2)and56cm-'(n=4),orabout25%ofthetotalIPshiffinducedbytheclu~ter.Based on this IP difference, isomer-selective ionization and electronic spectroscopy have been performed.

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