Isolation of 9,9'-bis-9-azabicyclo[3.3.1]nonane radical cation hexafluorophosphate, and its reversible oxidation to the dication
β Scribed by Nelsen, Stephen F.; Kessel, Carl R.
- Book ID
- 127172061
- Publisher
- American Chemical Society
- Year
- 1977
- Tongue
- English
- Weight
- 270 KB
- Volume
- 99
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Flash photolysis of bis [4,5di(methylsulfanyl)1,3-dithiol-2-ylidene]-9,10-dihydroanthracene (1) in chloroform leads to formation of the transient radical cation species 1 . which has a diagnostic broad absorption band at l max % 650 nm. This band decays to half its original intensity over a period o
## Abstract 4,9βDiethyl[1,4]dihydrodithiino[5,6β__f__]benzotrithiole (DTBT) gave a radical cation, DTBT(β’+), and a dication, DTBT(2+), on treatment with a singleβelectron oxidizing reagent. Both compounds showed an ESR signal, whereas the dication, generated by this procedure, was silent for ^1^H N