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Isolation and Study of the Intermediate [Dimethyl-N-(2-cyano-2-propyl)-ketenimine] Formed in the Decomposition of α,α'-Azoisobutyronitrile

✍ Scribed by Hammond, George S.; Trapp, Orlin D.; Keys, Richard T.; Neff, David L.


Book ID
126094022
Publisher
American Chemical Society
Year
1959
Tongue
English
Weight
665 KB
Volume
81
Category
Article
ISSN
0002-7863

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## Abstract Copolymerizations of styrene (S) with methyl methacrylate (MMA) and methacrylonitrile (MAN) at 60°C were performed with azoisobutyronitrile as initiator, enriched in its methyl groups with ^13^C. From the NMR spectrum of a copolymer it is possible to compare the numbers of initiator fra