Isolation and Structure of a Stable Molecule Containing a Silicon-Carbon Double Bond
✍ Scribed by Prof. Dr. Nils Wiberg; Dipl.-Chem. Gerhard Wagner; Dr. Gerhard Müller
- Publisher
- John Wiley and Sons
- Year
- 1985
- Tongue
- English
- Weight
- 237 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
on the occasion of his 70th birthday For a long time, unsaturated silicon compounds with multiple bonds to silicon have been thought to be unisolable at room temperature. [1] This situation changed profoundly in 1981. [2,3] During the past 25 years, intriguing progress has been achieved to generate
ands such as S, CSMe and eS2CNR2.[7.".'21 In the final products of these dimerizations, the two chelate ligands can adopt, in principle, either a cisoid (5) or a transoid (6) disposition. However, the factors leading to one or the other ge-0 0 :: ,\s-C I X L-C / x OC-Mn-S' OC-Mn-S' " oc' I I oc' I 5
The chemical reactivity of syn-3 was investigated. The experimental results showed that the central double bond of this system is inert toward chemical reactions. To determine the reactivity of this central double bond, we synthesized syn-and anti-7 and recorded their photoelectron spectra. Low firs