Synthesis of a New System Containing a Pyramidalized Double Bond: Lack of Reactivity of a Strongly Protected Pyramidalized Double Bond

✍ Scribed by Nurullah Saraçogˇlu; Metin Balci

• Publisher: John Wiley and Sons
• Year: 2001
• Tongue: German
• Weight: 107 KB
• Volume: 84
• Category: Article
• ISSN: 0018-019X
• DOI: 10.1002/1522-2675(20010321)84:3<707::aid-hlca707>3.0.co;2-p

✦ Synopsis

The chemical reactivity of syn-3 was investigated. The experimental results showed that the central double bond of this system is inert toward chemical reactions. To determine the reactivity of this central double bond, we synthesized syn-and anti-7 and recorded their photoelectron spectra. Low first-ionization potentials of synand anti-7 (7.6 eV) clearly indicated that these compounds should be highly reactive.