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Isolation and Structure Determination of new Iridals fromIris sibirica andIris versicolor

✍ Scribed by Marner, Franz-Josef ;Longerich, Irmgard


Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
382 KB
Volume
1992
Category
Article
ISSN
0947-3440

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✦ Synopsis


Abstract

Four novel iridals (compounds 8, 11, 12, and 13), representing new examples of these unusual monocyclic triterpenoids from sword lilies, have been isolated from rhizome extracts of I. sibirica and I. versicolor. Their structures have been elucidated by spectroscopic methods combined with oxidative degradation. Based on the stereochemistry of the 10‐deoxy‐17‐hydroxyiridal 13, the possible biosynthesis of these compounds is discussed.


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