\_Absorption spectra for Cu, Xg and Au atoms isolated in I-I 2, Dz, N2 and CH4 matrices are shown and the matrix in%ence on these spectra is evahated. Unlike the inezt gases, these matrices cause an unusually large crystal field splitting of the metal 2tom n P5,2 level. Distinct differences in the s
Isolation and Reactions of Metal Atoms in Matrices
β Scribed by Prof. Dr. George C. Pimentel
- Publisher
- John Wiley and Sons
- Year
- 1975
- Tongue
- English
- Weight
- 867 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
β¦ Synopsis
states are going to survive the trip and be able to exhibit some chemistry. The chemistry of the electronically excited state(s) can differ dramatically from that of the ground state, and one such system which nicely demonstrates this is the reaction of magnesium which alkyl halides (Scheme 11).
-1 9 6 " r CHB-CHZ-CHZ-C~ + Mg('S) -CH3-CHz-CHz-Cl/Mg deeply colored
π SIMILAR VOLUMES
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