𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Isolation and Characterization of the Osmium(V)–Imido Complex [OsV(Tp)(Cl)2(NH)]

✍ Scribed by My Hang V. Huynh; Peter S. White; Kevin D. John; Thomas J. Meyer

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
85 KB
Volume
113
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Synthesis of the Tetradentate Thioether
Synthesis of the Tetradentate Thioether Amine and Thioether Thiolate Ligands ′tpS2(NH2)2′ and ′tpS4′-H2 and Some Representative Six-Coordinate Ruthenium and Osmium Complexes [′tpS2(NH2)2′ =1,2-Bis(2-aminophenylthio)phenylene; ′tpS4′2– = 1,2-Bis(2-mercaptophenylthio)phenylene(2–)]
✍ Dieter Sellmann; Klaus Engl; Torsten Gottschalk-Gaudig; Frank W. Heinemann 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 217 KB 👁 2 views

Synthesis of the

Structural Characterization and Intramol
Structural Characterization and Intramolecular Aliphatic C−H Oxidation Ability of MIII(μ-O)2MIII Complexes of Ni and Co with the Hydrotris(3,5-dialkyl-4-X-pyrazolyl)borate Ligands Tp3.0.CO;2-C/asset/equation/tex2gif-sup-3.gif?v=1&t=h5lp536o&s=a03c9eb1fe277a993afb16d61a4b5e5e1fd6ae14" class="inlineGraphic"> (X=Me, H, Br) and Tp3.0.CO;2-C/asset/equation/tex2gif-sup-4.gif?v=1&t=h5lp536o&s=f62756419e66415fd41eb92c51dc480468265b22" class="inlineGraphic">
✍ Shiro Hikichi; Michito Yoshizawa; Yasuyuki Sasakura; Hidehito Komatsuzaki; Yoshi 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 531 KB

The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.