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Isoindolinones via a room temperature palladium nanoparticle-catalysed 3-component cyclative carbonylation–amination cascade

✍ Scribed by Ronald Grigg; Lixin Zhang; Simon Collard; Ann Keep

Book ID: 104254370
Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 142 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(03)01805-7

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✦ Synopsis

A room temperature 3-component cascade process involving nucleophilic substitution/carbonylation/amination, catalysed by palladium nanoparticles generated in situ from palladacycle 5, affords isoindolinones in good yields. The conversions correlate with the pK a values of the amines.

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