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Isocyanide insertion reactions. The role of isocyanide insertions in the metal assisted hydrogenation of isocyanides

โœ Scribed by Adams, Richard D.; Golembeski, Nancy M.

Book ID
126064090
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
308 KB
Volume
100
Category
Article
ISSN
0002-7863

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We have reported a series of insertion reactions of isocyanides into nitrogen-hydrogen of amine.1) oxygen-hydrogen of alcohol, 2) sulfur-hydrogen of thiol, 3) and silicone-hydrogen of silane4) to produce the corresponding derivatives of N-alkylformimidic acid in high yields.