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Is the Proton Affinity of Nitric Acid Larger Than the Proton Affinity of Methyl Nitrate? A Direct Experimental Answer

โœ Scribed by Cacace, Fulvio; Attina, Marina; de Petris, Giulia; Speranza, Maurizio


Book ID
126970315
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
569 KB
Volume
116
Category
Article
ISSN
0002-7863

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Determination of the H2O๎—ธNO+2 and CH3O(H
โœ L.S. Sunderlin; Robert R. Squires ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 427 KB

The binding energies of water and methanol to NO: have been measured 10 be 14.8 k 2.3 and 19.2 ? 2.3 kcal/mol, respectively, using energy-resolved collision-induced dissociation of H#-NO: and CH,O( H )-NO: in a flowing afterglow triple quadrupole apparatus. These values are used with literature ther