## Abstract The algebra of irreducible tensor operators is developed in the intermediate‐field coupling case. The Wigner‐Eckart theorem is formulated for a simple irreducible tensor operator as well as for the Kronecker and scalar products of these operators. The expressions required for the calcul
✦ LIBER ✦
Irreducible tensor operator methods in strong-field coupling
✍ Scribed by E. König; S. Kremer
- Book ID
- 104579155
- Publisher
- John Wiley and Sons
- Year
- 1977
- Tongue
- English
- Weight
- 642 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0020-7608
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✦ Synopsis
Abstract
The algebra of irreducible tensor operators is developed in the strong‐field coupling case. The method is of general applicability to any symmetry group G including nonsimply reducible groups and mixed configurations. The Wigner–Eckart theorem is given for irreducible tensor operators as well as for their Kronecker and scalar products. The expressions required for the calculation of ligand field splitting, Coulomb repulsion, spin–orbit interaction, and Zeeman effect are given in detail. Applications to problems in the spectroscopy and magnetism of transition metal compounds are referred to.
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