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Irreducible tensor operator methods in strong-field coupling

✍ Scribed by E. König; S. Kremer


Book ID
104579155
Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
642 KB
Volume
12
Category
Article
ISSN
0020-7608

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✦ Synopsis


Abstract

The algebra of irreducible tensor operators is developed in the strong‐field coupling case. The method is of general applicability to any symmetry group G including nonsimply reducible groups and mixed configurations. The Wigner–Eckart theorem is given for irreducible tensor operators as well as for their Kronecker and scalar products. The expressions required for the calculation of ligand field splitting, Coulomb repulsion, spin–orbit interaction, and Zeeman effect are given in detail. Applications to problems in the spectroscopy and magnetism of transition metal compounds are referred to.


📜 SIMILAR VOLUMES


Irreducible tensor operator methods in i
✍ E. König; S. Kremer 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 English ⚖ 656 KB

## Abstract The algebra of irreducible tensor operators is developed in the intermediate‐field coupling case. The Wigner‐Eckart theorem is formulated for a simple irreducible tensor operator as well as for the Kronecker and scalar products of these operators. The expressions required for the calcul