## Abstract The algebra of irreducible tensor operators is developed in the strong‐field coupling case. The method is of general applicability to any symmetry group __G__ including nonsimply reducible groups and mixed configurations. The Wigner–Eckart theorem is given for irreducible tensor operato
✦ LIBER ✦
Irreducible tensor operator methods in intermediate-field coupling
✍ Scribed by E. König; S. Kremer
- Book ID
- 104578476
- Publisher
- John Wiley and Sons
- Year
- 1974
- Tongue
- English
- Weight
- 656 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0020-7608
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✦ Synopsis
Abstract
The algebra of irreducible tensor operators is developed in the intermediate‐field coupling case. The Wigner‐Eckart theorem is formulated for a simple irreducible tensor operator as well as for the Kronecker and scalar products of these operators. The expressions required for the calculation of Coulomb repulsion, crystal field splitting, spin‐orbit interaction, and Zeeman effect are given in detail. Recent applications to various problems in spectroscopy and magnetism of transition metal compounds are referred to.
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