Iron(III)-Ethylenediaminetetraacetic Acid Mediated Aerobic Oxidation of α-Hydroxyketones: A Simple and Convenient Synthesis of α-Diketones.
✍ Scribed by T. Venkateshwar Rao; Rajendra S. Dongre; Suman L. Jain; Bir Sain
- Book ID
- 101933230
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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Aromatic a-hydroxyketones were easily oxidized by dioxygen in the presence of excess aldehyde or aldoacetal with catalytic amount of Co(II) or Fe(II1) complexes, under homogeneous and heterogeneous conditions. Co(acac), or Fe(acac), were the catalysts used in homogeneous phase reactions whereas Co(I
Iron(III)-Ethylenediaminetetraacetic Acid Mediated Oxidation of Thiols to Disulfides with Molecular Oxygen. -A simple environmentally acceptable method for the title oxidation under mild conditions is presented. It is noteworthy that the pH is important for the reaction time. -
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α-Lipoic acid / Structural analogues / Tricarbonyl(η 5 -pentadienyl)iron cations / Carbonyliron complexes / Diimide reduction Dithioester 10 was synthesized in 6 steps from tricarbonyl-also be of interest for the preparation of various labelled compounds and structural analogues. (diene)iron complex