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Iron(II) spin crossover complexes with branched long alkyl chain

โœ Scribed by Young Hoon Lee; Asuka Ohta; Yuki Yamamoto; Yasuka Komatsu; Kazuya Kato; Tetsuya Shimizu; Hideaki Shinoda; Shinya Hayami


Book ID
113856492
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
593 KB
Volume
30
Category
Article
ISSN
0277-5387

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The complexcompounds [Fe(otz)6](BF,)z (I), [Fe(dotz)el(BF.& (II) and [Fe(odetz)61(BF& (III) (otz=l+octyltetrazole, dotz =I-ndodecyl-tetrazole, odetz = I-n-octadecyl-tetrazole) with monodentate tetrazole ligands carryiq long alkyl chains in the l-position exhibit thermal high-spin (HS, $Ts) elow-spin

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## Abstract The unusual grinding effects observed in the 1D spin crossover polymer [FeL(bipy)]__~n~__ (**1**), with L being a tetradentate N~2~O~2~^2โ€“^ coordinating Schiff base type ligand {(3,3โ€ฒ)โ€[1,2โ€phenylenebis(iminomethylidyne)]bis(2,4โ€pentanedionato)(2โ€“)โ€__N,Nโ€ฒ,O^2^,O^2^โ€ฒ__} and bipy = 4,4โ€ฒโ€b