Iron(II) djenkolate: synthesis and properties
✍ Scribed by Petr Melnikov; Pedro P Corbi; Carlos Diaz Aguila; Marisa A Zacharias; Maurı́cio Cavicchioli; Antonio C Massabni
- Book ID
- 117619115
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 158 KB
- Volume
- 307
- Category
- Article
- ISSN
- 0925-8388
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## Abstract Treatment of anhydrous MCl~2~ (M = Mn, Fe) with (Ph~2~PMe~2~Si)~3~CH in toluene at elevated temperature resulted in the isolation of colorless (MnCl~2~{(Ph~2~PMe~2~Si)~3~CH}) (1) and light yellow (FeCl~2~{(Ph~2~PMe~2~Si)~3~CH}) (2) in high yield. These paramagnetic complexes have been c
Four kinds of novel CN-bridged Nin-Fe lu complexes, [NiL,(NC)Fe(CN)sI -, have been synthesized and characterized by elemental analysis, i.r. and u.v.-vis, spectral analysis, and magnetic moments. The formation of cyanide bridges is evident from the i.r. and u.v.-vis, spectra by the appearance of v(C