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Iron(II) bleomycin-mediated reduction of oxygen to water: an oxygen-17 NMR study

✍ Scribed by Barr, John R.; Van Atta, Reuel B.; Natrajan, Anand; Hecht, Sidney M.; Van der Marel, Gijs A.; Van Boom, Jacques H.


Book ID
125897210
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
452 KB
Volume
112
Category
Article
ISSN
0002-7863

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Water exchange of square-planar Pd(H,O):' has been studied as a function of temperature (240 to 345 K) and pressure (0.1 to 260 MPa, at 324 K) by measuring the I70-FT-NMR line-widths of the resonance from coordinated water at 27.11 and 48.78 MHz. The following exchange parameters were obtained: k:&8