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Iron porphyrin models of peroxidase enzymes: catalytic activity, regeneration, and oxidative degradation of mesoferriheme

✍ Scribed by Woo, Fanny S.; Cahiwat-Alquiza, Mariella; Kelly, Henry C.


Book ID
126154811
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
770 KB
Volume
29
Category
Article
ISSN
0020-1669

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## Abstract The heme‐thiolate protein chloroperoxidase (CPO) catalyzes the chlorination of activated Cο£ΏH bonds. A reaction mechanism is proposed for this enzymatic transformation (__Scheme 1__), and a new iron(III) porphyrinate complex 13 is synthesized containing pentafluorophenyl groups at two __