The halogenated Porphyrin, 2,12,13,17,l5,~~hy~nat~iron(III) chloride, [ Fe( TPPPBr,)Cl] , catalyzes the oxidation of cyclohexene in the presence of molecular oxygen or iodosobenzene. With PhIO, 77% epoxide is observed, consistent with a mechanism involving a high-valent metaI-oxo species. With dioxy
✦ LIBER ✦
Catalytic mechanisms and reactivity of peroxidases, catalases and iron–porphyrin model systems
✍ Scribed by Peter Jones
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 248 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0020-1693
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