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Iron Phosphinimide and Phosphinimine Complexes: Catalyst Precursors for Ethylene Polymerization

โœ Scribed by LePichon, Luc; Stephan, Douglas W.; Gao, Xiaoliang; Wang, Qinyan


Book ID
126444878
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
71 KB
Volume
21
Category
Article
ISSN
0276-7333

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โœ Qiu, Jiaoming; Yufei Li, ; Hu, Youliang ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 63 KB ๐Ÿ‘ 2 views

A new iron-based catalyst, 2,6-bis[(1-naphthanylimino)ethyl]pyridine iron(II) chloride I, has been successfully synthesized and characterized. Ethylene was polymerized by I/methylaluminoxane to give branched, low-density polymers with good activity. The result shows that the new diimino ligand has i