The Anion of the Pentacarbonyl[(trans-2,
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Emanuela Licandro; Stefano Maiorana; Laura Capella; Raffaella Manzotti; Antonio
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Article
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1998
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John Wiley and Sons
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English
β 297 KB
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The diastereoselective Michael addition of the title anion to are formed as a result of an unexpected intramolecular transfer of an oxygen atom from the nitro group to the Ξ±-hydrogenand Ξ±-methyl-substituted conjugated nitroalkenes leads to new Ξ³-nitrocarbene complexes and Ξ³-hydrocarbene atom, with e