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Iron in the Service of Chromium: The ortho-Benzannulation of trans,trans-Dienyl Fischer Carbene Complexes.

✍ Scribed by Yiqian Lian; William D. Wulff


Publisher
John Wiley and Sons
Year
2006
Weight
26 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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The diastereoselective Michael addition of the title anion to are formed as a result of an unexpected intramolecular transfer of an oxygen atom from the nitro group to the Ξ±-hydrogenand Ξ±-methyl-substituted conjugated nitroalkenes leads to new Ξ³-nitrocarbene complexes and Ξ³-hydrocarbene atom, with e