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Iron-Catalyzed Synthesis of Thioesters from Thiols and Aldehydes in Water

✍ Scribed by Huang, Yu-Ting; Lu, Shao-Yi; Yi, Chih-Lun; Lee, Chin-Fa

Book ID
121856127
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
727 KB
Volume
79
Category
Article
ISSN
0022-3263

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A General and Mild Synthesis of Thioesters and Thiols from Halides. -A variety of organic halides undergoes nucleophilic displacement with potassium thioacetate to yield thioesters under mild conditions. The generality of the method is tested with a broad spectrum of functionalities in the substrat