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Iron-Catalyzed Radical Oxidative Coupling Reaction of Aryl Olefins with 1,3-Dithiane

✍ Scribed by Du, Wenbin; Tian, Lixia; Lai, Junshan; Huo, Xing; Xie, Xingang; She, Xuegong; Tang, Shouchu


Book ID
123611561
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
726 KB
Volume
16
Category
Article
ISSN
1523-7060

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Coupling reactions of 2-aryl-1,3-dithiol
✍ Wen-Lung Cheng; Tien-Yau Luh πŸ“‚ Article πŸ“… 1992 πŸ› John Wiley and Sons 🌐 English βš– 338 KB

## Reactions of 2-aryl-l,3-dithiolane-S-oxides 1 with MeMgI in refluxing benzene-ether furnish a useful procedure for introducing the isopropenyl group. The reaction may proceed via a fragmentation-coupling process leading to the alkylative olefination product.