Iron-catalyzed epoxidation of olefins using hydrogen peroxide
β Scribed by Hasan, Kamrul; Brown, Nicole; Kozak, Christopher M.
- Book ID
- 111677231
- Publisher
- Royal Society of Chemistry
- Year
- 2011
- Tongue
- English
- Weight
- 254 KB
- Volume
- 13
- Category
- Article
- ISSN
- 1463-9262
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π SIMILAR VOLUMES
Epoxides are an important class of industrial chemicals that have been used as chemical intermediates. Catalytic epoxidation of olefins affords an interesting technology for their production. This review summarizes recent developments for the epoxidation of olefins with hydrogen peroxide catalyzed b
The highest turnovers reported so far in the epoxidation of olefins with hvdroaen peroxide are obtained under homoaeneous conditions with trioctyimethyla&nonium tungstate complexed by lipophilic neutral or anionic phosphorus ligands containing the P=O subunit.
Hydrotalcite-Catalyzed Epoxidation of Olefins Using Hydrogen Peroxide and Amide Compounds. -A triphasic oxidation system, consisting of aqueous H 2 O 2 , amide, solid hydrotalcite as base catalyst, and anionic surfactant in dichloroethane, is examined on various olefins. Isobutyramide is found to b