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Iron-Catalyzed Cross-Coupling Reactions of Terminal Alkynes with Vinyl Iodides

✍ Scribed by Xin Xie; Xiaobing Xu; Hongfeng Li; Xiaolei Xu; Jingyu Yang; Yanzhong Li

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
168 KB
Volume
351
Category
Article
ISSN
1615-4150

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✦ Synopsis

Abstract

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A convenient iron‐catalyzed cross‐coupling reaction of terminal alkynes with vinyl iodides is reported. The reaction was applicable to various acetylenes and vinyl iodides. The present reaction provides an efficient, environmentally friendly protocol to afford conjugated enyne derivatives in good to excellent yields under mild conditions.

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## Abstract An inexpensive and experimentally simple, iron‐catalyzed __N__‐arylation reaction of __NH__‐sulfoximines with aryl iodides is reported. This complementary method to the known palladium‐ and copper‐catalyzed ones features the use of a combination of environmentally friendly FeCl~3~ and _