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Iron-Catalyzed CN Cross-Coupling of Sulfoximines with Aryl Iodides

✍ Scribed by Arkaitz Correa; Carsten Bolm

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
177 KB
Volume
350
Category
Article
ISSN
1615-4150

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✦ Synopsis

Abstract

An inexpensive and experimentally simple, iron‐catalyzed N‐arylation reaction of NH‐sulfoximines with aryl iodides is reported. This complementary method to the known palladium‐ and copper‐catalyzed ones features the use of a combination of environmentally friendly FeCl~3~ and N,N′‐dimethylethylenediamine (DMEDA) as catalytic system and allows the efficient preparation of various N‐arylsulfoximines in high yields.

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Iron-Catalyzed Cross-Coupling Reactions
Iron-Catalyzed Cross-Coupling Reactions of Terminal Alkynes with Vinyl Iodides
✍ Xin Xie; Xiaobing Xu; Hongfeng Li; Xiaolei Xu; Jingyu Yang; Yanzhong Li 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 168 KB 👁 1 views

## Abstract magnified image A convenient iron‐catalyzed cross‐coupling reaction of terminal alkynes with vinyl iodides is reported. The reaction was applicable to various acetylenes and vinyl iodides. The present reaction provides an efficient, environmentally friendly protocol to afford conjugate