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Iron catalyzed atom transfer radical polymerization of methyl methacrylate using diphenyl-2-pyridylphosphine as a ligand

✍ Scribed by Zhigang Xue; Seok Kyun Noh; Won Seok Lyoo


Book ID
105736867
Publisher
The Polymer Society of Korea
Year
2007
Tongue
English
Weight
831 KB
Volume
15
Category
Article
ISSN
1598-5032

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## Abstract The iron(III)‐catalyzed atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) was successfully employed using tributylphosphine (TBP) and trimethylphosphite (TMP) as ligands in the absence of a reducing agent. The effects of solvent and initiator on polymerization of

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The atom transfer radical polymerization of styrene and methyl methacrylate with FeCl 2 /iminodiacetic acid as the catalyst system in bulk was successfully implemented at 70 and 110 Β°C, respectively. The polymerization was controlled: the molecular weight of the resultant polymer was close to the ca