Employing Imine Macrocycle Ligand in the Atom Transfer Radical Polymerization of Methyl Methacrylate
✍ Scribed by Amin, A.; Ayoub, M. H.; Abd El‐Ghaffar, M.; Rieger, B.
- Book ID
- 121206930
- Publisher
- Taylor and Francis Group
- Year
- 2005
- Tongue
- English
- Weight
- 451 KB
- Volume
- 42
- Category
- Article
- ISSN
- 1060-1325
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## Abstract The iron(III)‐catalyzed atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) was successfully employed using tributylphosphine (TBP) and trimethylphosphite (TMP) as ligands in the absence of a reducing agent. The effects of solvent and initiator on polymerization of
## Abstract The reverse atom transfer radical polymerization of methyl methacrylate was investigated in different solvents: xylene, __N,N__‐dimethylformamide, and pyridine. The polymerizations were uncontrolled, using 2,2′‐bipyridine as a ligand in xylene and pyridine because the catalyst (CuBr~2~/