Atom Transfer Radical Polymerization of Methyl Methacrylate in Water-Borne System
✍ Scribed by Jousset, Stéphanie; Qiu, Jian; Matyjaszewski, Krzysztof; Granel, Claude
- Book ID
- 127218889
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 141 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0024-9297
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## Abstract The reverse atom transfer radical polymerization of methyl methacrylate was investigated in different solvents: xylene, __N,N__‐dimethylformamide, and pyridine. The polymerizations were uncontrolled, using 2,2′‐bipyridine as a ligand in xylene and pyridine because the catalyst (CuBr~2~/
## Abstract Microwave irradiation (MI) was applied to the atom transfer radical bulk polymerization of methyl methacrylate. The influence of the amount of the refluxing solvent used for controlling the polymerization temperature, irradiation power, irradiation time, and initiator concentration on t