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Iron and copper catalyzed reaction of benzylamine with carbon tetrachloride: facile formation of 2,4,5- triphenylimidazoline derivatives

โœ Scribed by Jiro Tsuji; Kiyomi Sakai; Hisao Nemoto; Hideo Nagashima


Book ID
103691909
Publisher
Elsevier Science
Year
1983
Weight
476 KB
Volume
18
Category
Article
ISSN
0304-5102

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The reaction of 3-aryl-3-thiosemicarbazides 1a-d with carbon disulfide in alkaline medium affords the nonisolable sulfide salts 2a-d. The latter undergo in situ heterocyclization with some โฃ-halogenated compounds, e.g., 3a,b and 13, to afford polyfunctionally substituted 2,3-dihydrothiazoles 4a-e an