Iridoids from the Bark of Alstonia scholaris
✍ Scribed by Tao Feng; Xiang-Hai Cai; Zhi-Zhi Du; Xiao-Dong Luo
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- German
- Weight
- 173 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Four new 11‐noriridoids named scholareins A–D (1–4), along with three known derivatives, isoboonein (5), alyxialactone (6), and loganin (7), were isolated from EtOH extracts of the bark of Alstonia scholaris by chromatographic methods. Their structures were identified by extensive mass‐spectrometric and spectroscopic (especially 2D‐NMR) experiments.
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## Abstract Three new akuamillan‐type indole alkaloids, __i.e.__, 5‐methoxystrictamine (=methyl (5__β__,16__R__,19__E__)‐5‐methoxyakuammilan‐17‐oate; **1**), methyl (16__R__,19__E__)‐1,2‐dihydro‐16‐(hydroxymethyl)‐5‐oxoakuammilan‐17‐oate (**2**), and methyl (2__β__,16__R__,19__E__)‐4,5‐didehydro‐1,
Indole Alkaloids from the Leaves of Alstonia villosa in Sunbawa (Alstonia 6). -From the MeOH extract of the title leaves among seventeen alkaloids seven novel ones such as (I)-(III) are isolated. The structure of (III) is determined by X-ray analysis.
## Abstract Two new iridoid glycosides, named scyphiphorins A (**1**) and B (**2**), together with four known compounds, geniposidic acid (=(1__S__,4a__S__,7a__S__)‐1‐(__β__‐D‐glucopyranosyloxy)‐1,4a,5,7a‐tetrahydro‐7‐(hydroxymethyl)cyclopenta[__c__]pyran‐4‐carboxylic acid; **3**), 4‐(4‐hydroxy‐3‐m