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Iridium Complex Catalyzed Pauson—Khand-Type Reaction of Allenynes.

✍ Scribed by Takanori Shibata; Sho Kadowaki; Masaya Hirase; Kentaro Takagi

Publisher
John Wiley and Sons
Year
2003
Weight
114 KB
Volume
34
Category
Article
ISSN
0931-7597

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## Abstract An interesting rhodium‐catalyzed asymmetric aqueous Pauson–Khand‐type reaction was developed. A chiral atropisomeric dipyridyldiphosphane ligand was found to be highly effective in this system. This operationally simple protocol allows both catalyst and reactants to be handled under air