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Iridium-Catalyzed Hydrogen Transfer: Synthesis of Substituted Benzofurans, Benzothiophenes, and Indoles from Benzyl Alcohols

โœ Scribed by Anxionnat, Bruno; Gomez Pardo, Domingo; Ricci, Gino; Rossen, Kai; Cossy, Janine


Book ID
120546254
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
497 KB
Volume
15
Category
Article
ISSN
1523-7060

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Iridium-Catalyzed Selective Synthesis of
โœ Kyoji Tsuchikama; Yu-ki Hashimoto; Kohei Endo; Takanori Shibata ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 183 KB

## Abstract A directed cyclizationโ€dehydration cascade of ฮฑโ€aryloxy ketones and ฮฑโ€arylamino ketones was efficiently catalyzed by a cationic iridiumโ€BINAP complex, which afforded various types of 4โ€substituted benzofurans and indoles in high yields with complete regioselectivity. The newly developed